The reduction of nitro compounds is most preferred in the presence of

The reduction of nitro compounds is most preferred in the presence of
  1. $\mathrm{Pd} / \mathrm{H}_{2}$ in ethanol
  2. $\mathrm{Sn}+\mathrm{HCl}$
  3. finely divided Ni
  4. iron scrap and $\mathrm{HCl}$

Solution

Reduction with iron scrap and hydrochloric acid is preferred because $\mathrm{FeCl}_{2}$ formed gets hydrolysed to release hydrochloric acid during the reaction. Thus, only a small amount of hydrochloric acid is required to initiate the reaction. /

Asked in: JEE-TOPICTESTS-CHEMISTRY

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