The reactivity of compound Z with different halogens under appropriate conditions is given below: The…

The reactivity of compound Z with different halogens under appropriate conditions is given below:


The observed pattern of electrophilic substitution can be explained by

  1. The steric effect of the halogen
  2. The steric effect of the tert-butyl group
  3. The electronic effect of the phenolic group
  4. The electronic effect of the tert-butyl group

Solution

The reason is the steric hindrance of the tetra-butyl group which is attached to the benzene ring. That is why, the reactivity of compound Z with different halogens under the appropriate condition and electro-negativity of the halogens is Cl2 >Br2>I2

Asked in: JEE Advanced 2014 (Paper 1)

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