The reaction of toluene with $\mathrm{Cl}_2$ in presence of $\mathrm{FeCl}_3$ gives predominantly

The reaction of toluene with $\mathrm{Cl}_2$ in presence of $\mathrm{FeCl}_3$ gives predominantly
  1. benzoyl chloride
  2. benzyl chloride
  3. $o-$and $p-$chlorotoluene
  4. $m-$chlorotoluene

Solution

Due to $\mathrm{o}$ - and $\mathrm{p}$ - directing nature of $\mathrm{CH}_3$ group.
Hence, (C) is correct answer.

Asked in: JEE Main 2007

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