The ratio between RMS velocities of $\mathrm{H}_2$ at $50 \mathrm{~K}$ and $\mathrm{O}_2$ at $800…

The ratio between RMS velocities of $\mathrm{H}_2$ at $50 \mathrm{~K}$ and $\mathrm{O}_2$ at $800 \mathrm{~K}$ is
  1. 4 : 1
  2. 2 : 1
  3. 1 : 1
  4. 1 : 4

Solution

Root mean square speed $=\sqrt{\frac{3 R T}{M}}$ Given, $ \begin{aligned} M_1 & =\text { molar mass of } \mathrm{H}_2=2 \\ M_2 & =\text { molar mass of } \mathrm{O}_2=32 \\ T_1 & =50 \mathrm{~K}, T_2=800 \mathrm{~K} \end{aligned} $ On taking ratio of $r_1$ and $r_2$, we get $ \begin{aligned} & \frac{r_1}{r_2}=\sqrt{\frac{M_2 \times T_1}{M_1 \times T_2}}=\sqrt{\frac{32}{2}} \times \sqrt{\frac{T_1}{T_2}} \\ & \frac{r_1}{r_2}=\sqrt{16} \times \sqrt{\frac{50}{800}} \text { or } \frac{r_1}{r_2}=4 \times \frac{1}{4} \end{aligned} $ or $ \frac{r_1}{r_2}=\frac{1}{1}=1: 1 $ Hence, option (c) is correct

Asked in: AP EAMCET 2019 (20 Apr Shift 2)

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