The rate constant for a first order reaction is $20 \, \text{min}^{-1}$. The time required for the initial…

The rate constant for a first order reaction is $20 \, \text{min}^{-1}$. The time required for the initial concentration of the reactant to reduce to its $\frac{1}{32}$ level is ______ $\times 10^{-2} \, \text{min}$. (Nearest integer)

Solution

For a first order reaction, we know:
t1/2=0.693k=0.69320=0.03465 min
From the relation of half lives(where 'n' is the no. of half-lives):

12n=132

=125

Thus, No. of Half life =5

Time required =0.03465×5=0.17325 min=17.325×10-2 min

Asked in: JEE Main 2023 (31 Jan Shift 2)

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