The potential energy function for the force between two atoms in a diatomic molecule is approximately given…

The potential energy function for the force between two atoms in a diatomic molecule is approximately given by $U(x)=\frac{a}{x^{12}}-\frac{b}{x^6}$, where a and $b$ are constants and $x$ is the distance between the atoms. If the dissociation energy of the molecule is $D=\left[U(x=\infty)-U_{\text {at equilbrium }}\right], D$ is
  1. $\frac{b^2}{2 a}$
  2. $\frac{b^2}{12 a}$
  3. $\frac{b^2}{4 a}$
  4. $\frac{b^2}{6 a}$

Solution

$ \begin{aligned} & U(x)=\frac{a}{x^{12}}-\frac{b}{x^6} \\ & U(x=\infty)=0 \end{aligned} $ as, $\quad \mathrm{F}=-\frac{\mathrm{dU}}{\mathrm{dx}}=-\left[\frac{12 \mathrm{a}}{\mathrm{x}^{13}}+\frac{6 \mathrm{~b}}{\mathrm{x}^7}\right]$ at equilibrium, $\quad F=0$ $\begin{array}{ll}\therefore & x^6=\frac{2 a}{b} \\ \therefore & U_{\text {at equiltrium }}=\frac{a}{\left(\frac{2 a}{b}\right)^2}-\frac{b}{\left(\frac{2 a}{b}\right)}=\frac{-b^2}{4 a} \\ \therefore & D=\left[U(x=\infty)-U_{\text {at equilibium }}\right]=\frac{b^2}{4 a}\end{array}$

Asked in: JEE Main 2010

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