The pair(s) of coordination complexes/ions exhibiting the same kind of isomerism is (are)

The pair(s) of coordination complexes/ions exhibiting the same kind of isomerism is (are)
  1. Cr NH 3 5 Cl Cl 2  and  Cr NH 3 4 Cl 2 Cl
  2. Co NH 3 4 Cl 2 +  and  Pt NH 3 2 H 2 O Cl +
  3. Co Br 2 Cl 2 2 -  and  Pt Br 2 Cl 2 2 -
  4. Pt NH 3 3 NO 3 Cl  and  Pt NH 3 3 Cl Br

Solution

Cr NH 3 5 Cl Cl 2  and  Cr NH 3 4 Cl 2 Cl , both compounds will not show either structural or stereoisomerism.
Co NH 3 4 Cl 2 +  and  Pt NH 3 2 H 2 O Cl + , Ma4b2 type (octahedral), Ma2bc type (square planar) and both will show geometrical isomerism. ​
Co Br 2 Cl 2 2 -  and  Pt Br 2 Cl 2 2 - , Ma4b2 type (tetrahedral), Ma2b2 (square planar). ​
Pt NH 3 3 NO 3 Cl  and  Pt NH 3 3 Cl Br both will show ionisation isomerism. ​

Asked in: JEE Advanced 2013 (Paper 1)

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