The oxidation state and covalency of $\mathrm{Al}$ in $\left[\mathrm{AlCl}\left(\mathrm{H}_2…

The oxidation state and covalency of $\mathrm{Al}$ in $\left[\mathrm{AlCl}\left(\mathrm{H}_2 \mathrm{O}\right)_5\right]^{2+}$ respectively are
  1. +3 and 6
  2. +6 and 3
  3. +1 and 2
  4. -2 and 1

Solution

Oxidation state of $\mathrm{Al}$ in given compound $ x+(-1)+5(0)=+2 $ Therefore, $(x)=+3$ In aqueous solution, the water molecules are just interacting electrostatically and not actually bonding. Their partially negative end is pulled by aluminium (+3) oxidation state in an ion-dipole interaction. $\mathrm{Cl}^{-}$is similarly pulled by $\mathrm{Al}(+3)$ oxidation state. While covalency is 6 because 6 coordinate bonds are formed ( 5 by $\mathrm{H}_2 \mathrm{O}$ and 1 by $\mathrm{Cl}^{-}$). Hence, the oxidation state and covalency of $\left[\mathrm{AlCl}\left(\mathrm{H}_2 \mathrm{O}\right)_5\right]^{2+}$ are +3 and 6 respectively

Asked in: AP EAMCET 2020 (22 Sep Shift 2)

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