The order of increasing reactivity of the following compounds towards H C l will be 1 C H 2 = C H 2 ( 2 ) (…
The order of increasing reactivity of the following compounds towards will be
Solution
Compounds:
1. \(\mathrm{CH}_2=\mathrm{CH}_2\) (Ethene)
2. \(\left(\mathrm{CH}_3ight)_2 \mathrm{C}=\mathrm{CH}_2\) (Isobutene)
3. \(\mathrm{CH}_3 \mathrm{CH}=\mathrm{CHCH}_3\) (2-Butene)
Reaction Mechanism:
The addition of HCl to an alkene occurs via the formation of a carbocation intermediate. The stability of the resulting carbocation determines the reactivity towards HCl. More stable carbocations lead to a faster reaction.
Carbocation Stability:
1. Primary carbocation \(\left(1^{\circ}ight)\) — least stable
2. Secondary carbocation \(\left(2^{\circ}ight)\) - more stable
3. Tertiary carbocation \(\left(3^{\circ}ight)\) — most stable