The order of increasing reactivity of the following compounds towards H C l will be 1 C H 2 = C H 2 ( 2 ) (…

The order of increasing reactivity of the following compounds towards HCl will be
1 CH2=CH2
(2) (CH3)2C=CH2
3 CH3CH=CHCH3
  1. 1<2<3
  2. 1<3<2
  3. 3<2<1
  4. 2<1<3

Solution

Compounds: 1. \(\mathrm{CH}_2=\mathrm{CH}_2\) (Ethene) 2. \(\left(\mathrm{CH}_3ight)_2 \mathrm{C}=\mathrm{CH}_2\) (Isobutene) 3. \(\mathrm{CH}_3 \mathrm{CH}=\mathrm{CHCH}_3\) (2-Butene) Reaction Mechanism: The addition of HCl to an alkene occurs via the formation of a carbocation intermediate. The stability of the resulting carbocation determines the reactivity towards HCl. More stable carbocations lead to a faster reaction. Carbocation Stability: 1. Primary carbocation \(\left(1^{\circ}ight)\) — least stable 2. Secondary carbocation \(\left(2^{\circ}ight)\) - more stable 3. Tertiary carbocation \(\left(3^{\circ}ight)\) — most stable

Asked in: JEE-TOPICTESTS-CHEMISTRY

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