The octahedral complex of a metal ion M 3 + with four monodentate ligands L 1 ,   L 2 ,   L 3…

The octahedral complex of a metal ion M3+ with four monodentate ligands L1, L2, L3 and L4 absorb wavelengths in the region of red, green, yellow and blue, respectively. The increasing order of ligand strength of the four ligands is
  1. L4 < L3 < L2 < L1
  2. L1 < L3 < L2 < L4
  3. L3 < L2 < L4 < L1
  4. L1 < L2 < L4 < L3

Solution

The colors of wavelengths are absorbed in decreasing order of wavelengths.

λ red > λ yellow > λ green > λ blue

as ΔE=hcλ

Δ E Red < Δ E Yellow < Δ E Green < Δ E Blue

L1 < L3 < L2 < L4

As the order of ligand field strength provides the order of relative crystal field splitting energies.  

Asked in: JEE Main 2014 (06 Apr)

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