The number of moles of $\mathrm{KMnO}_4$ reduced by one mole of $\mathrm{KI}$ is alkaline medium is:

The number of moles of $\mathrm{KMnO}_4$ reduced by one mole of $\mathrm{KI}$ is alkaline medium is:
  1. one
  2. two
  3. five
  4. one fifth

Solution

In alkaline medium: Related Theory In acidic medium: $\mathrm{MnO}_4^{-}+8 \mathrm{H}^{+}+5 e^{-} \longrightarrow$ $\mathrm{Mn}_2+4 \mathrm{H}_2 \mathrm{O}$ In basic medium: $\mathrm{MnO}_4^{-}+e^{-} \rightarrow \mathrm{MnO}_4^{2-}$ In neutral medium: $\mathrm{MnO}_4^{-}+4 \mathrm{H}^{+}+3 e^{-} \longrightarrow$ $\mathrm{MnO}_2+2 \mathrm{H}_2 \mathrm{O}$

Asked in: NEET 2005

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