The number of \(120^{\circ}, \mathrm{Cl}-\mathrm{P}-\mathrm{Cl}\) angles in phosphorus pentachloride are

The number of \(120^{\circ}, \mathrm{Cl}-\mathrm{P}-\mathrm{Cl}\) angles in phosphorus pentachloride are
  1. 3
  2. 6
  3. 9
  4. 1

Solution

Geometry and structure of phosphorus pentachloride \(\left(\mathrm{PCl}_5\right)\) molecule is trigonal bipyramidal where P-atom is \(s p^3 d\)-hybridised. Three \(\mathrm{Cl}\)-atom are present at equatorial positions with \(\angle \mathrm{Cl}-\mathrm{P}-\mathrm{Cl}=120^{\circ}\) and two \(\mathrm{Cl}\)-atoms are present at axial positions with \(\angle \mathrm{Cl}-\mathrm{P}-\mathrm{Cl}=90^{\circ}\).

Asked in: AP EAMCET 2020 (18 Sep Shift 2)

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