The molecules having square pyramidal geometry are

1. $\mathrm{BrF}_5 ~\&~ \mathrm{PCl}_5$
2. $\mathrm{SbF}_5 ~\&~ \mathrm{PCl}_5$
3. $\mathrm{SbF}_5 ~\&~ \mathrm{XeOF}_4$
4. $\mathrm{BrF}_5 ~\&~ \mathrm{XeOF}_4$

Solution

$\mathrm{BrF}_5$ : Square pyramedal
$\mathrm{XeOF}_4$ : Square pyramedal
$\mathrm{SbF}_5$ : Trigonal bipyramidal
$\mathrm{PCl}_5$ : Trigonal bipyramidal

Asked in: JEE Main 2025 (28 Jan Shift 1)

Practice more Chemical Bonding and Molecular Structure questions on Aicharya