The mechanism of Sn1 reaction is given as: R - X ⟶ R ⊕ X ⊖ ⟶ R ⊕  …

The mechanism of Sn1 reaction is given as:

R-XRXR  XYR-Y+X              lon pair      Solvent                             Speparated ion                                      pair

A student writes general characteristics based on the given mechanism as :
(a) The reaction is favoured by weak nucleophiles.
(b) R would be easily formed if the substituents are bulky y
(c) The reaction is accompanied by recemization
(d) The reaction is favoured by non-polar solvents.

Which observations are correct?

  1. (a) and (b)
  2. (a) and (c)
  3. (a), (b) and (c)
  4. (b) and (d)

Solution

Above reaction isSN1 reaction as it proceed via formation of carbocation. Polar protic solvent is more suitable for SN1 and recemisation takes place.

Asked in: JEE Main 2020 (03 Sep Shift 1)

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