The Lassiagne's extract is boiled with dil HNO 3 before testing for halogens because,
- is soluble in
- Silver halides are soluble in
- is soluble in
- and are decomposed by
Solution
The Lassaigne’s extract is first boiled with dil. HNO3 to decompose cyanide or sulphide of sodium (NaCN or Na2S) formed during Lassaigne’s test. These ions would otherwise interfere with silver nitrate test for halogen.
Hence option D is the answer.
Asked in: JEE Main 2024 (30 Jan Shift 1)