The Lassiagne's extract is boiled with dil HNO 3 before testing for halogens because,

The Lassiagne's extract is boiled with dil HNO3 before testing for halogens because,
  1. AgCN is soluble in HNO3
  2. Silver halides are soluble in HNO3
  3. Ag2 S is soluble in HNO3
  4. Na2 S and NaCN are decomposed by HNO3

Solution

The Lassaigne’s extract is first boiled with dil. HNO3 to decompose cyanide or sulphide of sodium (NaCN or Na2S) formed during Lassaigne’s test. These ions would otherwise interfere with silver nitrate test for halogen.

NaCN ( aq ) + HNO3 ( aq )  NaNO3 ( aq ) + HCN ()

Na2S ( aq ) + 2 HNO3 ( aq )  2 NaNO3 ( aq ) + H2S (  )

Hence option D is the answer.

Asked in: JEE Main 2024 (30 Jan Shift 1)

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