The increasing order of the p K b   of the following compund is: ( A ) ( B ) ( C ) ( D )

The increasing order of the pKb  of the following compund is:
(A)
(B)
(C)
(D)
  1. (B)<(D)<(C)<(A)
  2. (B)<(D)<(A)<(C)
  3. (C)<(A)<(D)<(B)
  4. (A)<(C)<(D)<(B)

Solution

pKb=-logkb          kbpkb
Basic character in amine and its derivative
α -ve charge density
α availability of lone pair
α+M  α 1-M
α+HC  α 1-HC
α+I  α 1-I
Kb basic character B>D>A>(C)
pKb=B<D<A<C

Asked in: JEE Main 2019 (12 Apr Shift 1)

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