The increasing order of the acidity of the following carboxylic acids is:

The increasing order of the acidity of the following carboxylic acids is:
  1. III $ < $ II $ < $ IV $ < $ I
  2. I $ < $ III $ < $ II $ < $ IV
  3. IV $ < $ II $ < $ III $ < $ I
  4. II $ < $ IV $ < $ III $ < $ I

Solution

The increasing order of the acidity of the carboxylic acids is III $ < $ II $ < $ IV $ < $ I. In aromatic acids, electron withdrawing groups like $\mathrm{Cl},-\mathrm{CN},-\mathrm{NO}_2$ increases the acidity, whereas electron releasing groups like $\mathrm{CH}_3,-\mathrm{OH},-\mathrm{OCH}_3,-\mathrm{NH}_2$ decreases the acidity.

Asked in: JEE Main 2018 (15 Apr Shift 2 Online)

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