The incorrect statement is.

The incorrect statement is.
  1. The spin-only magnetic moments of FeH2O62+ and CrH2O62+ are nearly similar.
  2. The spin-only magnetic moment of NiNH34H2O22+ is 2.83 BM.
  3. The gemstone, ruby, has Cr3+ ions occupying the octahedral sites of beryl.
  4. The color of CoClNH352+ is violet as it absorbs the yellow light.

Solution

A FeH2O62+, Fe2+3d64 unpaired electron

CrH2O62+, Cr2+3d44 unpaired electron

B NiNH34H2O22+=Ni2+3d8

2 unpaired electron

μm=2.83B.M

C In gemstone, ruby has Cr3+ ion occupying the octahedral sites of aluminium oxide Al2O3 normally occupied by Al3+ ion.

D Complimentary color of violet is yellow.

Asked in: JEE Main 2019 (10 Apr Shift 2)

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