The hybridization and magnetic behaviour of cobalt ion in [ Co ( NH 3 ) 6 ] 3 + complex, respectively is
- and diamagnetic
- and paramagnetic
- and diamagnetic
- and paramagnetic
Solution
In , is in oxidation state with the configuration . In the presence of a strong field ligand, the 3d electrons undergo pairing and leaving two d-orbitals empty. Hence, the hybridisation is which forms an inner orbital octahedral complex. The complex is diamagnetic as it has no unpaired electrons.

So, the correct option is C
Asked in: JEE Main 2023 (24 Jan Shift 2)