The hybridization and magnetic behaviour of cobalt ion in [ Co ( NH 3 ) 6 ] 3 + complex, respectively is

The hybridization and magnetic behaviour of cobalt ion in [Co(NH3)6]3+ complex, respectively is
  1. sp3d2 and diamagnetic
  2. d2sp3 and paramagnetic
  3. d2sp3 and diamagnetic
  4. sp3d2 and paramagnetic

Solution

In [Co(NH3)6]3+, Co is in +3 oxidation state with the configuration 3d6. In the presence of NH3 a strong field ligand, the 3d electrons undergo pairing and  leaving two d-orbitals empty. Hence, the hybridisation is d2sp3 which forms an inner orbital octahedral complex. The complex is diamagnetic as it has no unpaired electrons.

So, the correct option is C

Asked in: JEE Main 2023 (24 Jan Shift 2)

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