The frequency of light emitted for the transition $n=4$ to $n=2$ of the $\mathrm{He}^{+}$ is equal to the…
- $n=2$ to $n=1$
- $n=3$ to $n=2$
- $n=4$ to $n=3$
- $n=3$ to $n=1$
Solution
$=R_{H}(2)^{2}\left(\frac{1}{2^{2}}-\frac{1}{4^{2}}ight)=R_{H}\left(\frac{1}{(1)^{2}}-\frac{1}{(2)^{2}}ight)$
For H, $\bar{v}=\frac{1}{\lambda}=R_{H}\left(\frac{1}{n_{1}^{2}}-\frac{1}{n_{2}^{2}}ight)$
For same frequency, $R_{H}\left(\frac{1}{(1)^{2}}-\frac{1}{(2)^{2}}ight)=R_{H}\left(\frac{1}{n_{1}^{2}}-\frac{1}{n_{2}^{2}}ight)$
$\therefore \quad \frac{1}{n_{1}^{2}}-\frac{1}{n_{2}^{2}}=\frac{1}{1^{2}}-\frac{1}{2^{2}}$
$\therefore \quad n_{1}=1 \& n_{2}=2$ *
Asked in: JEE-TOPICTESTS-CHEMISTRY