The following data were obtained during the first order thermal decomposition of a gas A at constant volume:…

The following data were obtained during the first order thermal decomposition of a gas A at constant volume:

Ag2 Bg+Cg

S. No                 Time/s                 Total pressure/(atm)

 1.                        0                        0.1

 2.                      115                     0.28

The rate constant of the reaction is _______ ×10-2s-1 (nearest integer)       

Solution

t=0t=115 sec. Ag0.10.1-x 2Bg2x+Cg2x

0.1+2x = 0.28

2x=0.18

x=0.09

K=1115ln0.10.1-0.09

=0.0200sec-1

=2×10-2sec-1

Asked in: JEE Main 2024 (01 Feb Shift 2)

Practice more Chemical Kinetics questions on Aicharya