The following complexes are given (1) trans- $\left[\mathrm{Co}\left(\mathrm{NH}_{3}ight)_{4}…

The following complexes are given
(1) trans- $\left[\mathrm{Co}\left(\mathrm{NH}_{3}ight)_{4} \mathrm{I}_{2}ight]^{\oplus}$
(2) cis- $\left[\mathrm{Co}\left(\mathrm{NH}_{3}ight)_{2}(\mathrm{en})_{2}ight]^{3+}$
(3) trans- $\left[\mathrm{Co}\left(\mathrm{NH}_{3}ight)_{2}(\mathrm{en})_{2}ight]^{3+}$
(4) $\left[\mathrm{NiI}_{4}ight]^{2-}$
(5) $\left[\mathrm{TiF}_{6}ight]^{2-}$
(6) $\left[\mathrm{CoF}_{6}ight]^{3-}$
Choose the correct code.
  1. 4,5 are coloured; 6 is colourless
  2. 2 is optically active; 1,3 are optically inactive
  3. 1, 2 are optically active; 3 optically inactive
  4. 4 is coloured; 5,6 are colourless

Solution

2 is optically active; 1,3 are optically inactive *

Asked in: JEE-TOPICTESTS-CHEMISTRY

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