The electrode potential of the following half cell at 298   K X X 2 + 0 . 001 M ‖ Y 2 + 0 . 01 M…

The electrode potential of the following half cell at 298 K

XX2+0.001MY2+0.01MY is _____ ×10-2 V (Nearest integer)

Given : EX2+X0=-2.36 V

EY2+Y0=+0.36 V

2.303RTF=0.06 V

Solution

The net cell reaction can be written as follows,

X+Y2+Y+X2+

Ecell0=Ecathode0-Eanode0(Both are SRP values)

ECell0=0.36--2.36=2.72 V

Now, the Nernst equation is,

Ecell=Ecell0-0.06nlogX2+Y2+

n=The number of electrons involved in the net reaction.

ECell=2.72-0.062log0.0010.01

=2.72+0.03=2.75 V

=275×10-2 V

Asked in: JEE Main 2023 (30 Jan Shift 2)

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