The difference in the number of unpaired electrons of a metal ion in its high-spin and low-spin octahedral…

The difference in the number of unpaired electrons of a metal ion in its high-spin and low-spin octahedral complexes is two. The metal ion is:
  1. Fe2+
  2. Co2+
  3. Ni2+
  4. Mn2+

Solution

The electronic configuration for Co2+z=27=4s03d7 

When it combines with weak ligands (high spin complex),t2g2,2,1 eg1,1, it has 3 unpaired electrons, whereas when it bonds with strong ligands (low spin complex), t2g2,2,2 eg1,0, then, it has 1 unpaired electron.

The difference in number of unpaired electrons is equal to two.

Asked in: JEE Main 2019 (10 Jan Shift 2)

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