The corrosion of iron is essentially an electrochemical phenomenon. What are the cell reactions involving in…

The corrosion of iron is essentially an electrochemical phenomenon. What are the cell reactions involving in the phenomenon?
  1. Fe is oxidised to Fe3+ and H2O is reduced to O22-.
  2. Fe is oxidised to Fe2+ and H2O is reduced to O2-.
  3. Fe is oxidised to Fe2+ and H2O is reduced to O2.
  4. Fe is oxidised to Fe2+ and dissolved oxygen in water is reduced to OH-

Solution

2Fe2Fe2++4e- (anodic reaction)

O2+2H2O+4e-4OH- (cathodic reaction)

The overall reaction is

 2Fe+O2+2H2O2FeOH2

Fe(OH)2 may be dehydrated to iron oxide FeO or further oxidized to Fe(OH)3 and then dehydrated to iron rust, Fe2O3.

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Asked in: JEE-TOPICTESTS-CHEMISTRY

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