The correct statements from the following are : (A) $\mathrm{Tl}^{3+}$ is a powerful oxidising agent (B)…

The correct statements from the following are :
(A) $\mathrm{Tl}^{3+}$ is a powerful oxidising agent
(B) $\mathrm{Al}^{3+}$ does not get reduced easily
(C) Both $\mathrm{Al}^{3+}$ and $\mathrm{Tl}^{3+}$ are very stable in solution
(D) $\mathrm{Tl}^{+}$is more stable than $\mathrm{Tl}^{3+}$
(E) $\mathrm{Al}^{3+}$ and $\mathrm{Tl}^{+}$are highly stable
Choose the correct answer from the options given below :
  1. (A), (B), (C), (D) and (E)
  2. (A), (B), (D) and (E) only
  3. (B), (D) and (E) only
  4. (A), (C) and (D) only

Solution

(i) True, $\mathrm{T} \ell^{+}$is more stable than $\mathrm{T} \ell^{3+}$, due to inert pair effect. So $\mathrm{T} \ell^{3+}$ is a powerful oxidising agent.
(ii) True, $\mathrm{E}_{\mathrm{Al}^{3+/ A 1}}^0=-1.66 \mathrm{~V}$. So it is difficult to reduce $\mathrm{A} \ell^{3+}$. So $\mathrm{A} \ell^{3+}$ is highly stable.
(iii) False, as $\mathrm{T} \ell^{3+}$ is unstable
(iv) True, $\mathrm{T} \ell^{+}$is more stable than $\mathrm{T} \ell^{3+}$
(v) True, $\mathrm{A} \ell^{3+}$ and $\mathrm{T} \ell^{+}$are highly stable

Asked in: JEE Main 2025 (07 Apr Shift 2)

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