The correct order of the spin-only magnetic moments of the following complexes is: ( I ) C r H 2 O 6 B r 2 (…

The correct order of the spin-only magnetic moments of the following complexes is:
(I) CrH2O6Br2
(II) Na4Fe(CN)6
(III) Na3FeC2O43Δ0>P
(IV) Et4N2CoCl4
  1. III>I>IV>II
  2. III>I>II>IV
  3. I>IV>III>II
  4. III>IV>III

Solution

As μs=nn+2
Complex (II) Fe+2S.F.Lt2g2,2,2eg0,0μs=0
Complex (I) Cr+2W.F.Lt2g1,1,1eg1,0μs=24B.M
Complex (IV) Co+2W.F.Leg2,2,t2g^1,1,1,μs=15B.M
Complex (III) Fe+3S.F.Lt2g1,1,1eg0,0μs=3B.M

Asked in: JEE Main 2020 (09 Jan Shift 2)

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