The correct order of reactivity for reactions involving cleavage of $\mathrm{C}-\mathrm{Cl}$ bond in…

The correct order of reactivity for reactions involving cleavage of $\mathrm{C}-\mathrm{Cl}$ bond in following compounds is
  1. I $\gt$ II $\gt$ III
  2. II $\gt$ III $\gt$ I
  3. III $\gt$ I $\gt$ II
  4. III $\gt$ II $\gt$ I

Solution

Greater the number of electron withdrawing groups $\left(-\mathrm{NO}_2\right)$ at $\mathrm{o} / \mathrm{p}$ position, greater is the reactivity. Hence, 2,4,6-trinitrochlorobenzene has the highest reactivity.

Asked in: MHT CET 2024 (04 May Shift 1)

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