The correct order of increasing acidic strength among the following is

The correct order of increasing acidic strength among the following is
  1. phenol < ethanol < chloroacetic acid < acetic acid
  2. ethanol < phenol < chloroacetic acid < acetic acid
  3. ethanol < phenol < acetic acid < chloroacetic acid
  4. chloroacetic acid < acetic acid < phenol \( < \) ethanol

Solution

The correct order of increasing acidic strength is : ethanol \( < \) phenol \( < \) acetic acid \( < \) chloroacetic acid Phenol is more acidic than ethanol because in phenol, the phenoxide ion obtained on deprotonation is stabilised by resonance, which is not possible in case on ethanol. Also carboxylic acids are more acidic than alcohols and phenols as the carboxylate ion is stabilised by resonance. Chloroacetic acid is more acidic than acetic acid due to inductive effect of chlorine atom which stabilises the carboxylate anion. Hence, the correct option is (c).

Asked in: AP EAMCET 2020 (21 Sep Shift 2)

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