The correct increasing order for the wavelengths of absorption in the visible region for the complexes of Co…

The correct increasing order for the wavelengths of absorption in the visible region for the complexes of Co3+ is:
  1. Coen33+, CoNH363+, CoH2O63+
  2. CoH2O63+, Coen33+, CoNH363+
  3. CoH2O63+, CoNH363+, Coen33+
  4. CoNH363+, Coen33+, CoH2O63+

Solution

The order of the ligand in the spectrochemical series
H2O<NH3<en
Absorbed wavelength1Absorbed energy
Thus, the order of observed energy is:
CoH2O63+<CoNH363+<Coen33+
Hence, the wavelength absorbed will be in the opposite order i.e., Coen33+< CoNH363+< CoH2O63+.

Asked in: NEET 2017

Practice more Coordination Compounds questions on Aicharya