The bond order and the magnetic characteristic of C N - are

The bond order and the magnetic characteristic of CN- are
  1. 212, diamagnetic
  2. 3, diamagnetic
  3. 3, paramagnetic
  4. 212, paramagnetic

Solution

According to MOT (If z is internuclear axis) The configuration of

CN:σ1s2,σ*1s2,σ2s2,σ*2s2,π2px2=π2py2,σ2pz2
 
Bond order=number of electrons in bonding orbitals-number of electrons in anti-bonding orbitals2

Bond order = 1 2 (104)=3

CN is diamagnetic due to absence of unpaired electron.

Asked in: JEE Main 2020 (07 Jan Shift 2)

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