The absolute enthalpy of neutralisation of the reaction: : $\mathrm{MgO}_{(s)}+2 \mathrm{HCl}_{(a q)}$…

The absolute enthalpy of neutralisation of the reaction: : $\mathrm{MgO}_{(s)}+2 \mathrm{HCl}_{(a q)}$ $\rightarrow \mathrm{MgCl}_{2(a q)}+\mathrm{H}_2 \mathrm{O}_{(\cap}$ will be:
  1. $-57.33 \mathrm{~kJ} \mathrm{~mol}^{-1}$
  2. greater than $-57.33 \mathrm{~kJ} \mathrm{~mol}^{-1}$
  3. less than $-57.33 \mathrm{~kJ} \mathrm{~mol}^{-1}$
  4. $57.33 \mathrm{~kJ} \mathrm{~mol}^{-1}$

Solution

$\mathrm{MgO}$ is salt of weak base. Thus, enthalpy of neutralisation for $\mathrm{MgO}$ will be less than $-57.33 \mathrm{~kJ} \mathrm{~mol}^{-1}$. Related Theory The enthalpy of neutralization of any strong acid with a strong base is always the same, i.e., $57.1 \mathrm{~kJ}$. This is because the strong acids, strong bases and the salts they form, are all completely ionized in dilute aqueous solution.

Asked in: MHT CET Full Test 10

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