Spin only magnetic moment in BM of Fe CO 4 C 2 O 4 + is :

Spin only magnetic moment in BM of FeCO4C2O4+ is :
  1. 5.92
  2. 1
  3. 0
  4. 1.73

Solution

In Fe(CO)4C2O4+

Oxidation no. of Fe=+3 

26Fe+3=Ar183 d54 s0 

CO is a Strong field ligand, so paring occurs against the Hund's rule. 

Fe+3=t2g2,2,1 eg0,0 

Number of unpaired electron =1 

so magnetic moment μ=nn+2 B.M. =11+2=3=1.73 BM

Asked in: JEE Main 2021 (31 Aug Shift 2)

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