Sea water contains 29 . 25 % NaCl and 19 % MgCl 2 by weight of solution. The normal boiling point of the sea…

Sea water contains 29.25%NaCl and 19%MgCl2 by weight of solution. The normal boiling point of the sea water is C (Nearest integer) Assume 100% ionization for both NaCl and MgCl2 Given: KbH2O=0.52 K kg mol-1 Molar mass of NaCl and MgCl2 is 58.5 and 95 g mol-1 respectively.

Solution

Molality of solution=moles of solutemass of solvent×1000

Number of moles NaCl =29.2558.5=0.5

Number of moles of MgCl2=1995=0.2

NaCl=0.551.75×1000

MgCl2=0.251.75×1000

ΔTb=i1 m1+i2 m2kb

Tb= Elevation in boiling point

i=Van't Hoff factor

m = molality

kb = molal elevation constant

Tb=2×0.5×100051.75×3×0.2×100051.75×0.52

= 16.077

Boiling point of sea water

=116.077°C

116°C (Nearest integer)

Asked in: JEE Main 2023 (13 Apr Shift 2)

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