$n$-Propyl alcohol and isopropyl alcohol can be chemically distinguished by which reagent?
$n$-Propyl alcohol and isopropyl alcohol can be chemically distinguished by which reagent?
$\mathrm{PCl}_5$
Reduction
Oxidation with potassium dichromate
Ozonolysis
Solution
Isopropyl alcohol and n-propyl alcohol can be chemically distinguished by oxidation with potassium dichromate.n-propyl alcohol on oxidation with potassium dichromate gives an aldehyde. Isopropyl alcohol on oxidation with potassium dichromate gives a ketone. During oxidation of potassium dichromate, solution of potassium dichromate turns bluegreen in the reactions. For isopropyl alcohol this colour change is fast and for $n$-propyl alcohol the colour change is slow.
Isopropyl alcohol and n-propyl alcohol are examples of position isomers.In isopropyl alcohol, the hydroxyl group is present in the second carbon atom whereas in n-propyl alcohol the hydroxyl group is present in the first carbon atom.