On changing $\mathrm{N}_{2}$ to $\mathrm{N}_{2}^{+}$, the dissociation energy of $\mathrm{N}-\mathrm{N}$…

On changing $\mathrm{N}_{2}$ to $\mathrm{N}_{2}^{+}$, the dissociation energy of $\mathrm{N}-\mathrm{N}$ bond $\ldots . .$ and on changing $\mathrm{O}_{2}$ to $\mathrm{O}_{2}^{+}$ the dissociation energy of O-O bond....
  1. increases, decreases
  2. decreases, increases
  3. decreases in both cases
  4. increases in both cases

Solution

On changing $\mathrm{N}_{2}$ to $\mathrm{N}_{2}^{+}$, B.O. decreases from 3 to $2.5$ whereas on changing $\mathrm{O}_{2}$ to $\mathrm{O}_{2}^{+}$, B.O. increases from 2 to 2.5. In former case, the bond dissociation energy decreases and in the latter case, it increases.

Asked in: JEE-TOPICTESTS-CHEMISTRY

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