N O 2 required for a reaction is produced by the decomposition of N 2 O 5 in C C l 4 as per the equation, 2…

NO2 required for a reaction is produced by the decomposition of N2O5 in CCl4 as per the equation,
2N2O5g4NO2g+O2g.
The initial concentration of N2O5 is 3.00 mol L-1 and it is 2.75 mol L-1 after 30 minutes. The rate of formation of NO2 is:
  1. 1.667×10-2  molL-1  min-1
  2. 8.333×10-3molL-1min-1
  3. 4.167×10-3molL-1min-1
  4. 2.083×10-3molL-1min-1

Solution

Rate of reaction in terms of rate of disappearance of N2O5(s)
-dN2O5dt=12dNO2dt=2dO2dt=rate of Reaction
-(-3+1.75)30=rate of reaction
--0.2530=8.3×10-3mol L-1min-1
=253000=8.3×10-3=12× rate of formation of O2
8.3×10-3=12dNO2dt
1.66×10-2m/min =d[NO2]dt

Asked in: JEE Main 2019 (12 Apr Shift 2)

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