N 0 /4 atoms of X(g) are converted into X + (g) by energy E 1 . N 0 /4 atoms of X(g) are converted into X –…

N0/4 atoms of X(g) are converted into X+(g) by energy E1. N0 /4 atoms of X(g) are converted into X(g) by energy E2. Hence, ionisation potential and electron affinity of X(g) are :
  1. 4 E 1 N 0 , 4 E 1 - E 2 N 0
  2. 4 E 1 N 0 , 4 E 2 N 0
  3. E 1 - E 2 N 0 , 4 E 2 N 0
  4. None is correct

Solution

X g X + g + e -

If I ionisationh energy then

       N 0 4 I = E 1

       I = 4 E 1 N 0

If E is electron-affinity then

X g + e - X - g

N 0 4 E = E 2

             E = 4 E 2 N 0 .

Asked in: JEE-TOPICTESTS-CHEMISTRY

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