N 0 2 atoms of X g are converted into X +   g by energy E 1 . N 0 2 atoms of X g are converted into X -…

N02 atoms of Xg are converted into X+ g by energy E1.N02 atoms of Xg are converted into X-g by energy E2 . , then ionization potential and electron affinity of Xg respectively are
  1. 2E1N0,2E1-E2N0
  2. 2E1N0,2E2N0
  3. E1-E2N0,2E2N0
  4. None is correct

Solution

The ionization energy and electron affinity of \(x(g)\) are, ionization energy and electron affinity of \(x(g)\) are \(\frac{2 E_1}{A_0}, \frac{2 E_2}{A_0}\). The ionization energy for the formula is found as \(\begin{aligned} & \mathrm{X} ightarrow \mathrm{X}^{+} ; \mathrm{IE}_1 \\ & \frac{\mathrm{N}_0}{2} \mathrm{I}=\mathrm{E}_1 \\ & \mathrm{I}=\frac{2 \mathrm{E}_1}{\mathrm{~N}_0} \end{aligned}\) The electron affinity for the formula is found as \(\begin{aligned} & \mathrm{X} ightarrow \mathrm{X}^{-} ; \mathrm{EA}_1 \\ & \frac{\mathrm{N}_0 \mathrm{E}}{2}=\mathrm{E}_2 \\ & \mathrm{E}=\frac{2 \mathrm{E}_2}{\mathrm{~N}_4} \end{aligned}\) Hence, the ionization energy and electron affinity of \(X(g)\) are ionization energy and electron affinity of \(X(g)\) are \(\frac{2 E_1}{A_0}, \frac{2 E_2}{A_0}\)

Asked in: JEE-TOPICTESTS-CHEMISTRY

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