More number of oxidation states are exhibited by the actinoids than by the lanthanoids. The main reason for…

More number of oxidation states are exhibited by the actinoids than by the lanthanoids. The main reason for this is:
  1. more active nature of the actinoids
  2. more energy difference between $5 f$ and $6 d$ orbitals than that between $4 f$ and $5 d$ orbitals
  3. lesser energy difference between $5 f$ and $6 d$ orbitals than that between $4 f$ and $5 d$ orbitals
  4. greater metallic character of the lanthanoids than that of the corresponding actinoids

Solution

Actinides exhibit more number of oxidation states than lanthanides because of lesser energy difference between the $5 f$ and $6 d$ orbitals than that between the $4 f$ and $5 d$ orbitals. Related Theory Actinides have a very small energy gap between $5 f$ and $6 d$ orbitals, so they can easily form a variety of configurations and hence they are found to be stable in various oxidation states. Lanthanides are comparatively less electropositive than actinides and due to that reason, they are less reactive than actinides.

Asked in: NEET 2006

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