Match the following based on valence bond theory. \begin{array}{llll} \hline & Hybridisation & Geometry &…
Match the following based on valence bond theory.
\begin{array}{llll}
\hline & Hybridisation & Geometry & \multicolumn{1}{c}{\begin{array}{l}
Complex \\
structure
\end{array}} \\
\hline (A) & s p^3 & (i) \begin{array}{l}
Square \\
planar
\end{array} & (p) \left[\mathrm{Fe}(\mathrm{CN})_6\right]^{3-} \\
\hline (B) & d^2 s p^3 & (ii) Tetrahedral & (q) \left.[\mathrm{ZnCl}]_4\right]^{2-} \\
\hline (C) & d s p^2 & (iii) Octahedral & (r) \left[\mathrm{Ni}\left(\mathrm{NH}_3\right)_4\right]^{2+} \\
\hline & & & (s) \left[\mathrm{Ag}(\mathrm{CN})_2\right]^{-} \\
\hline
\end{array}
- (A-ii-q), (B-iii-p), (C-i-r)
- (A-ii-q), (B-iii-r), (C-i-s)
- (A-i-q), (B-iii-p), (C-ii-r)
- (A-ii-r), (B-iii-s), (C-i-q)
Solution
According to VBT,
Hence, correct match is (A-ii-q), (B-iii-p), (C-i-r).
Asked in: AP EAMCET 2021 (25 Aug Shift 2)
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