Match the chemical conversions in List I with the appropriate reagents in List II and select the correct…

Match the chemical conversions in List I with the appropriate reagents in List II and select the correct answer using the code given below the lists :
 
 List - I   List - II 
 (A)   (P)  i HgOAc2; ii NaBH4
 (B)   (Q)  NaOEt
 (C)   (R)  Et-Br
 (D)   (S)  i BH3; ii H2O2/NaOH
  1. a-p;b-r;c-q;d-s;
  2. a-q;b-r;c-s;d-p;
  3. a-q;b-r;c-p;d-s;
  4. a-q;b-p;c-r;d-s;

Solution

A tertiary alkyl halide with strong base undergoes elimination reaction, while a primary alkyl halide with t-butoxide gives ether by a substitution reaction. Alkenes undergo hydration (addition of water) by Hydroboration-Oxidation, giving anti-Markovnikov's products and by Oxymercuration-Demercuration, giving Markovnikov's products.

Asked in: JEE Advanced 2013 (Paper 2)

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