Match each coordination compound in List-I with an appropriate pair of characteristics from List-II and…

Match each coordination compound in List-I with an appropriate pair of characteristics from List-II and
select the correct answer using the code given below the lists
en=H2NCH2CH2NH2 ;atomic numbers :Ti=22, Cr=24;Co=27;Pt=78
 
  List – I   List – II
A. CrNH34Cl2Cl P. Paramagnetic and exhibits ionization isomerism
B. TiH2O5 ClNO32 Q. Diamagnetic and exhibits cis - trans isomerism
C. PtenNH3ClNO3 R. Paramagnetic and exhibits cis - trans isomerism
D. CoNH34NO32NO3 S. Diamagnetic and exhibits ionization isomerism
  1. a-r;b-p;c-s;d-q;
  2. a-s;b-r;c-p;d-q;
  3. a-q;b-s;c-r;d-p;
  4. a-q;b-p;c-s;d-r;

Solution

(P) CrNH34Cl2Cl  Paramagnetic and exhibits cis-trans isomerism
(Q) TiH2O5 ClNO32  Paramagnetic and exhibits ionization isomerism
(R) PtenNH3ClNO3  Diamagnetic and exhibits ionization isomerism
(S) CoNH34NO32NO3 Diamagnetic and exhibits cis - trans isomerism

Asked in: JEE Advanced 2014 (Paper 2)

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