Which of the following statements are not correct? A. The electron gain enthalpy of F is more negative than…

Which of the following statements are not correct?

A. The electron gain enthalpy of F is more negative than that of Cl.

B. Ionization enthalpy decreases in a group of periodic table.

C. The electronegativity of an atom depends upon the atoms bonded to it.

D. Al2O3 and NO are examples of amphoteric oxides.

Choose the most appropriate answer from the options given below:

  1. A, B, C and D
  2. A, B and D only
  3. B and D only
  4. A, C and D only

Solution

A is incorrect. F and Cl belong to the same group of the periodic table. The electron gain enthalpy usually becomes less negative on moving down a group. However, in this case, the value of the electron gain enthalpy of Cl is more negative than that of F. This is because the atomic size of F is smaller than that of Cl

B is correct (ionisation energy decreases down the group).

C is incorrect (Electronegativity is a fixed property of an element and is typically measured on scales such as the Pauling scale or the Mulliken scale.). 

D is incorrect. The oxides which behave as both acidic and basic oxides are called amphoteric oxides. . Here Al2O3 is amphoteric oxide and NO is neutral oxide.

Hence, A, C and D are incorrect.

Asked in: JEE Main 2023 (13 Apr Shift 1)

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