Sucrose hydrolyses in acid solution into glucose and fructose following first order rate law with a…

Sucrose hydrolyses in acid solution into glucose and fructose following first order rate law with a half-life of 3.33 h at 25°C. After 9 h, the fraction of sucrose remaining is f. The value of log101f is ________ ×10-2. (Rounded off to the nearest integer)

[Assume: In10=2.303, ln 2=0.693]

Solution

C12H22O11+H2Ot1/2=103hrorderC6H12O6Glucose+C6H12O6Fructose

t=0  a=A0

t=9hr  a-x=At

from I order kinetic: k×t2.303=logA0At

ln2×9103×2.303=log1f

0.693×9×323.03=log1f

log1f=0.81246=81.24×10-2

x=81

Asked in: JEE Main 2021 (24 Feb Shift 2)

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