Match List I with List II: List I (Mixture) List II (Separation Technique) (A) CHCl 3 + C 6 H 5 NH 2 I Steam…

Match List I with List II:

  List I (Mixture)   List II
(Separation
Technique)
(A) CHCl3+C6H5NH2 I Steam distillation
(B) C6H14+C5H12 II Differential
extraction
(C) C6H5NH2+H2O III Distillation
(D) Organic compound in H2O IV Fractional
distillation
  1. A-IV, B-I, C-III, D-II
  2. A-III, B-IV, C-I, D-II
  3. A-II, B-I, C-III, D-IV
  4. A-III, B-I, C-IV, D-II

Solution

Chloroform (b.p 334 K) and aniline (b.p. 457 K) are easily separated by the technique of distillation.

One of the technological applications of fractional distillation is to separate different fractions of crude oil in the petroleum industry.

Aniline is separated by steam distillation technique from aniline – water mixture.

When an organic compound is present in an aqueous medium, it is separated by shaking it with an organic solvent in which it is more soluble than in water.

Hence, correct matching is given by the below table:

List I (Mixture) List II
(Separation
Technique)
CHCl3+C6H5NH2 Distillation
C6H14+C5H12 Fractional
distillation
C6H5NH2+H2O Steam distillation
Organic compound in H2O Differential
extraction

Asked in: JEE Main 2023 (30 Jan Shift 2)

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