Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R .…

Given below are two statements: one is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : The energy required to form Mg2+from Mg is much higher than that required to produce Mg+

Reason R:Mg2+ is small ion and carry more charge than Mg+

In the light of the above statements, choose the correct answer from the options given below.

  1. Both A and R are true but R is NOT the correct explanation of A
  2. A is true but R is false
  3. A is false but R is true
  4. Both A and R are true and R is the correct explanation of A

Solution

Mg have 2 electrons in valance shell and after donation of 2 electrons it converts into Mg2+ ion and attains inert gas configuration, now to ionize one more electron from inert gas configuration is very difficult, hence it is easy to ionize Mg to Mg2+.  IE2 is always greater than IE1 because on removal of e-, size decreases and effective nuclear charge increases.So Assertion is correct.

Mg2+ is a smaller ion than Mg+ and has a greater charge density. This means that Mg2+ has a stronger attraction to its electrons than Mg+ and requires more energy to remove an electron from it. So reason is also correct.

Asked in: JEE Main 2023 (10 Apr Shift 2)

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