Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R.…

Given below are two statements: One is labelled as Assertion A and the other is labelled as Reason R.

Assertion A : H2Te is more acidic than H2 S.

Reason R: Bond dissociation enthalpy of H2Te is lower than H2 S.
In the light of the above statements. Choose the most appropriate from the options given below.

  1. Both A and R are true but R is NOT the correct explanation of A.
  2.  Both A and R are true and R is the correct explanation of A.
  3. A is false but R is true.
  4. A is true but R is false.

Solution

Bond enthalpy, also referred to as bond energy or bond dissociation energy, is the energy required to break a particular covalent bond in one mole of molecule in a gaseous state.

The bond dissociation enthalpy of H2Te is lower than that of H2S.

As a result, less energy is required to break the H2Te bond, releasing H+ is easier, and the acidity of H2Te is greater.

H2S, on the other hand, has a high bond dissociation energy and so has lower acidity.

Hence, Both A and R are true and R is the correct explanation of A.

Asked in: JEE Main 2024 (30 Jan Shift 2)

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