For the reaction SO 2 ( g ) + 1 2 O 2 ( g ) ⇌ SO 3 ( g ) , the percentage yield of product at different…

For the reaction SO2(g)+12O2(g)SO3(g), the percentage yield of product at different pressures is shown in the figure. Then, which among the following is true?

  1. Pressure has no effect
  2. P1<P2<P3
  3. P1>P2>P3
  4. P1=P2=P30

Solution

Given the options: 1. Pressure has no effect: This is incorrect because pressure does affect the equilibrium of reactions involving gases. 2. \(P_1 < P_2 < P_3\) : If pressure increases, the yield of the product \(\mathrm{SO}_3\) should increase. Therefore, this would mean that \(P_1\) (lowest pressure) has the lowest yield, \(P_2\) (intermediate pressure) has a higher yield, and \(P_3\) (highest pressure) has the highest yield. 3. \(P_1 > P_2 > P_3\) : This implies that the yield decreases with increasing pressure, which is contrary to what we expect. 4. \(P_1=P_2=P_3 \neq 0\) : This would imply that pressure has no effect on the yield, which contradicts Le Chatelier's Principle. Conclusion: The correct option is: (2) \(P_1 < P_2 < P_3\) This means that as pressure increases, the yield of \(\mathrm{SO}_3\) increases.

Asked in: JEE-TOPICTESTS-CHEMISTRY

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