Lanthanoid ions with $4 f^7$ configuration are : (A) $\mathrm{Eu}^{2+}$ (B) $\mathrm{Gd}^{3+}$ (C)…

Lanthanoid ions with $4 f^7$ configuration are :
(A) $\mathrm{Eu}^{2+}$
(B) $\mathrm{Gd}^{3+}$
(C) $\mathrm{Eu}^{3+}$
(D) $\mathrm{Tb}^{3+}$
(E) $\mathrm{Sm}^{2+}$
Choose the correct answer from the options given below :
  1. (A) and (D) only
  2. (B) and (C) only
  3. (A) and (B) only
  4. (B) and (E) only

Solution

$\begin{aligned} & { }_{63} \mathrm{Eu}^{2+}-[\mathrm{Xe}] 4 \mathrm{f}^7 6 \mathrm{~s}^0 \\ & { }_{64} \mathrm{Gd}^{3+}-[\mathrm{Xe}] 4 \mathrm{f}^7 5 \mathrm{~d}^0 6 \mathrm{~s}^0 \\ & { }_{63} \mathrm{Eu}^{3+}-[\mathrm{Xe}] 4 \mathrm{f}^6 6 \mathrm{~s}^0 \\ & { }_{65} \mathrm{~Tb}^{3+}-[\mathrm{Xe}] 4 \mathrm{f}^8 6 \mathrm{~s}^0 \\ & { }_{62} \mathrm{Sm}^{2+}-[\mathrm{Xe}] 4 \mathrm{f}^6 6 \mathrm{~s}^0 \\ & \mathrm{Eu}^{2+} \& \mathrm{Gd}^{3+}\end{aligned}$

Asked in: JEE Main 2025 (22 Jan Shift 1)

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